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link.springer.com/article/10.100...0831-016-0057-5

Somerville, M.A. The Strength and Density of Green and Reduced Briquettes Made with Iron Ore and Charcoal. J. Sustain. Metall. 2, 228–238 (2016). https://doi.org/10.1007/s40831-016-0057-5

Composite briquettes or pellets consisting of iron ore, carbon, and a binder are a source of direct reduced iron (DRI). In the handling of green and reduced briquettes, high strength is important to minimize briquette breakdown. The use of charcoal as a source of carbon, rather than coal provides a way of introducing renewable carbon into the ironmaking process. Composite briquettes were made with Australian hematite iron ore, low volatile charcoal and 2 % starch as a binder. The carbon-to-iron mass ratio was varied between 0.18 and 0.26. The green briquettes were heated to either 1300 or 1350 °C for times varying from 3 to 15 min. After heating, the briquettes were tested for compressive strength, density, and the degree of iron metallization. The aim of the work was to determine the key strength forming features of the briquettes during heating and reduction. Dried green briquettes, made with a starch binder, were found to be very strong and required a force of at least 3800 N to yield under compression. After heating for 3 min, the briquettes lost strength rapidly before regaining strength at longer heating times of 10 and 15 min. Increasing the C/Fe ratio in the briquette mix decreased the strength and density, and increased the iron metallization of the heated briquettes. Briquette strength also increased with increasing time from 10 to 15 min and heating temperature from 1300 to 1350 °C. These observations can be explained in terms of the distance between iron oxide particles in the briquette mix. At low C/Fe ratios, iron oxide particles will be relatively close together which facilitates the development of a connected slag network which acts as a binder and increases briquette strength.